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Chiral GC Columns for the separation of enantiomers Cyclodextrin Derivatives suspended in Polysiloxanes |
Capillary columns with cyclodextrin derivatives can be used for the separation of broad range of enantiomers. For most of the compounds no specific derivatisation is needed, in some cases simple acetylation or methylation of polar groups is necessary. To achieve a maximum of seperation efficency and resolution the cyclodextrin derivatives are suspended in midpolar polysiloxanes. These columns are very durable and stable.
The mechanism of chiral recognition is not known in detail. So it´s difficult to predict the cyclodextrin that shows the best resolution. That's the reason why we offer seven different cyclodextrin phases.
BGB 173 |
50% 2,3-diacetyl-6-tert-butyldimethylsilyl-alpha-cyclodextrin |
BGB 175 | 50% 2,3-diacetyl-6-tert-butyldimethylsilyl-gamma-cyclodextrin |
BGB 176 | 30% 2,3-dimethyl-6-tert-butyldimethylsilyl-beta-cyclodextrin |
BGB 176SE | 30% 2,3-dimethyl-6-tert-butyldimethylsilyl-beta-cyclodextrin |
BGB 177 | 30% 2,6-dimethyl-3-phenyl-beta-cyclodextrin |
BGB 178 | 30% 2,6-diethyl-6-tert-butyldimethylsilyl-beta-cyclodextrin |
BGB 178PH | 30% 2,6-dimethyl-6-tert-butyldimethylsilyl-beta-cyclodextrin |